Cargando…

Well-Defined Aryl-Fe(II) Complexes in Cross-Coupling and C–H Activation Processes

[Image: see text] Herein we explore the intrinsic organometallic reactivity of iron embedded in a tetradentate N(3)C macrocyclic ligand scaffold that allows the stabilization of aryl-Fe species, which are key intermediates in Fe-catalyzed cross-coupling and C–H functionalization processes. This stud...

Descripción completa

Detalles Bibliográficos
Autores principales:	Magallón, Carla, Planas, Oriol, Roldán-Gómez, Steven, Luis, Josep M., Company, Anna, Ribas, Xavi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490821/ https://www.ncbi.nlm.nih.gov/pubmed/36158566 http://dx.doi.org/10.1021/acs.organomet.1c00100

Ejemplares similares

C(sp2)–H Amination Reactions Mediated by Metastable Pseudo-O(h) Masked Aryl-Co(III)-nitrene Species
por: Capdevila, Lorena, et al.
Publicado: (2022)

Unravelling the mechanism of cobalt-catalysed remote C–H nitration of 8-aminoquinolinamides and expansion of substrate scope towards 1-naphthylpicolinamide
por: Chu, Melody, et al.
Publicado: (2019)

Mechanistic insights into the S(N)2-type reactivity of aryl-Co(iii) masked-carbenes for C–C bond forming transformations
por: Planas, O., et al.
Publicado: (2018)

Au(iii)-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis
por: Serra, Jordi, et al.
Publicado: (2017)

Bis-Phenoxo-Cu(II)(2) Complexes: Formal Aromatic Hydroxylation via Aryl-Cu(III) Intermediate Species
por: Ribas, Xavi, et al.
Publicado: (2020)

Aerobic C–C and C–O bond formation reactions mediated by high-valent nickel species
por: Smith, Sofia M., et al.
Publicado: (2019)

Mechanism of the Aryl–F Bond-Forming Step from Bi(V) Fluorides
por: Planas, Oriol, et al.
Publicado: (2022)

Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts
por: Planas, Oriol, et al.
Publicado: (2020)

Hemilabile MIC^N ligands allow oxidant-free Au(i)/Au(iii) arylation-lactonization of γ-alkenoic acids
por: Font, Pau, et al.
Publicado: (2022)

Comparative profiling of well-defined copper reagents and precursors for the trifluoromethylation of aryl iodides
por: Kaplan, Peter T, et al.
Publicado: (2017)

Triethylenetetramine-Based Semiconducting Fe(III) Metallogel: Effective Catalyst for Aryl–S Coupling
por: Dhibar, Subhendu, et al.
Publicado: (2020)

A DFT Study on Fe(I)/Fe(II)/Fe(III) Mechanism of the Cross-Coupling between Haloalkane and Aryl Grignard Reagent Catalyzed by Iron-SciOPP Complexes
por: Sharma, Akhilesh K., et al.
Publicado: (2020)

Dual gold and photoredox catalysed C–H activation of arenes for aryl–aryl cross couplings
por: Gauchot, V., et al.
Publicado: (2017)

Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides
por: Sit, Wing-Nga, et al.
Publicado: (2013)

Influences of Alkyl and Aryl Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization
por: Guo, Lihua, et al.
Publicado: (2016)

Selective Hydrogenation of Aldehydes Using a Well‐Defined Fe(II) PNP Pincer Complex in Biphasic Medium
por: Weber, Stefan, et al.
Publicado: (2018)

The Effect of Alkyl Chain Length on Well-Defined Fluoro-Arylated Polythiophenes for Temperature-Dependent Morphological Transitions
por: Ochiai, Yuto, et al.
Publicado: (2020)

Highly Efficient and Selective Hydrogenation of Aldehydes: A Well-Defined Fe(II) Catalyst Exhibits Noble-Metal Activity
por: Gorgas, Nikolaus, et al.
Publicado: (2016)

N-Arylation of 3-Formylquinolin-2(1H)-ones Using Copper(II)-Catalyzed Chan–Lam Coupling
por: Valencia, Jhesua, et al.
Publicado: (2022)

Controlling Regioselectivity in Palladium‐Catalyzed C−H Activation/Aryl–Aryl Coupling of 4‐Phenylamino[2.2]paracyclophane
por: Zippel, Christoph, et al.
Publicado: (2020)

Multimetallic Catalysis Enabled Cross-Coupling of Aryl Bromides with Aryl Triflates
por: Ackerman, Laura K.G., et al.
Publicado: (2015)

N(2)H(4) as traceless mediator for homo- and cross- aryl coupling
por: Lv, Leiyang, et al.
Publicado: (2018)

Infrared Irradiation‐Assisted Solvent‐Free Pd‐Catalyzed (Hetero)aryl‐aryl Coupling via C−H Bond Activation
por: Albano, Gianluigi, et al.
Publicado: (2021)

Aryl Bromides and Aryl Chlorides for the Direct Arylation of Benzylic Amines Mediated by Ruthenium(II)
por: Dastbaravardeh, Navid, et al.
Publicado: (2013)

LiCl-Accelerated Multimetallic Cross-Coupling of Aryl Chlorides with Aryl Triflates
por: Huang, Liangbin, et al.
Publicado: (2019)

Tuning the Covering on Gold Surfaces by Grafting Amino-Aryl Films Functionalized with Fe(II) Phthalocyanine: Performance on the Electrocatalysis of Oxygen Reduction
por: Olguín, Camila F., et al.
Publicado: (2021)

Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
por: Ding, Qiuping, et al.
Publicado: (2012)

Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
por: Wang, Tao, et al.
Publicado: (2019)

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids
por: Bandar, Jeffrey S., et al.
Publicado: (2016)

Ru-Catalyzed C–H Arylation of Fluoroarenes with Aryl Halides
por: Simonetti, Marco, et al.
Publicado: (2016)

Metal-free C–H arylation of imidazoheterocycles with aryl hydrazines
por: Jana, Sourav, et al.
Publicado: (2018)

Palladium-catalysed C–H arylation of benzophospholes with aryl halides
por: Xu, Shibo, et al.
Publicado: (2022)

Ruthenium-Catalyzed C–H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides
por: Huang, Liangbin, et al.
Publicado: (2016)

Recent Advances in Transition-Metal-Catalyzed, Directed Aryl C–H/N–H Cross-Coupling Reactions
por: Henry, Martyn C., et al.
Publicado: (2017)

Coupling Dinitrogen and Hydrocarbons through Aryl Migration
por: McWilliams, Sean F., et al.
Publicado: (2020)

Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp(2) C—H Bonds of N-Aryl-2-amino Pyridine Derivatives
por: Koley, Moumita, et al.
Publicado: (2012)

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane
por: Wang, Feng, et al.
Publicado: (2019)

A mechanistic investigation of the photoinduced, copper-mediated cross-coupling of an aryl thiol with an aryl halide
por: Johnson, Miles W., et al.
Publicado: (2016)

Nickel/biimidazole-catalyzed electrochemical enantioselective reductive cross-coupling of aryl aziridines with aryl iodides
por: Wang, Yun-Zhao, et al.
Publicado: (2023)

Practical Ni-Catalyzed Aryl–Alkyl Cross-Coupling of Secondary Redox-Active Esters
por: Cornella, Josep, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_j17m7dq42h2ppjki98cq9a173a