Diastereoselectivity of the Addition of Propargylic Magnesium Reagents to Fluorinated Aromatic Sulfinyl Imines

[Image: see text] The addition of propargylmagnesium bromide to fluorinated aromatic sulfinyl imines gave homopropargyl amines with total regio- and diastereoselection. Complete reversal of diastereoselectivity can be achieved in some cases using coordinating (THF) or noncoordinating (DCM) solvents....

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Detalles Bibliográficos
Autores principales: Llobat, Alberto, Escorihuela, Jorge, Fustero, Santos, Medio-Simón, Mercedes
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490847/
https://www.ncbi.nlm.nih.gov/pubmed/33881896
http://dx.doi.org/10.1021/acs.orglett.1c01076

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490847/
https://www.ncbi.nlm.nih.gov/pubmed/33881896
http://dx.doi.org/10.1021/acs.orglett.1c01076

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