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A direct method to access various functional arylalkoxysilanes by Rh-catalysed intermolecular C–H silylation of alkoxysilanes
Efficient protocols for intermolecular C–H silylations of unactivated arenes and heteroarenes with HMe(2)SiOEt are disclosed. The silylations are catalysed by a Rh-complex (0.5 mol%) derived from commercially available [Rh(coe)(2)Cl](2) and (S,S)-Ph-BPE in the presence of cyclohexene at 100 °C, furn...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491085/ https://www.ncbi.nlm.nih.gov/pubmed/36320708 http://dx.doi.org/10.1039/d2sc03727k |