Interfacial electric fields catalyze Ullmann coupling reactions on gold surfaces

The electric fields created at solid–liquid interfaces are important in heterogeneous catalysis. Here we describe the Ullmann coupling of aryl iodides on rough gold surfaces, which we monitor in situ using the scanning tunneling microscope-based break junction (STM-BJ) and ex situ using mass spectro...

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Detalles Bibliográficos
Autores principales: Stone, Ilana B., Starr, Rachel L., Hoffmann, Norah, Wang, Xiao, Evans, Austin M., Nuckolls, Colin, Lambert, Tristan H., Steigerwald, Michael L., Berkelbach, Timothy C., Roy, Xavier, Venkataraman, Latha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491086/
https://www.ncbi.nlm.nih.gov/pubmed/36320717
http://dx.doi.org/10.1039/d2sc03780g

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