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Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE)....
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9498718/ https://www.ncbi.nlm.nih.gov/pubmed/36135301 http://dx.doi.org/10.3390/gels8090589 |
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author | Norjeli, Muhammad Faishal Tamchek, Nizam Osman, Zurina Mohd Noor, Ikhwan Syafiq Kufian, Mohd Zieauddin Ghazali, Mohd Ifwat Bin Mohd |
author_facet | Norjeli, Muhammad Faishal Tamchek, Nizam Osman, Zurina Mohd Noor, Ikhwan Syafiq Kufian, Mohd Zieauddin Ghazali, Mohd Ifwat Bin Mohd |
author_sort | Norjeli, Muhammad Faishal |
collection | PubMed |
description | Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE). The printed PUA GPE was then characterized through several techniques, such as Fourier transform infrared (FTIR), electrochemical impedance spectroscopy (EIS), X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The printed GPE exhibited high ionic conductivity of 1.24 × 10(−3) S cm(−1) at low-lithium-salt content (10 wt.%) in ambient temperature and favorable thermal stability to about 300 °C. The FTIR results show that addition of LiClO(4) to the polymer matrix caused a shift in carbonyl, ester and amide functional groups. In addition, FTIR deconvolution peaks of LiClO(4) show 10 wt.% has the highest amount of free ions, in line with the highest conductivity achieved. Finally, the PUA GPE was printed into 3D complex structure to show SLA flexibility in designing an electrolyte, which could be a potential application in advanced battery fabrication. |
format | Online Article Text |
id | pubmed-9498718 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-94987182022-09-23 Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application Norjeli, Muhammad Faishal Tamchek, Nizam Osman, Zurina Mohd Noor, Ikhwan Syafiq Kufian, Mohd Zieauddin Ghazali, Mohd Ifwat Bin Mohd Gels Article Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE). The printed PUA GPE was then characterized through several techniques, such as Fourier transform infrared (FTIR), electrochemical impedance spectroscopy (EIS), X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The printed GPE exhibited high ionic conductivity of 1.24 × 10(−3) S cm(−1) at low-lithium-salt content (10 wt.%) in ambient temperature and favorable thermal stability to about 300 °C. The FTIR results show that addition of LiClO(4) to the polymer matrix caused a shift in carbonyl, ester and amide functional groups. In addition, FTIR deconvolution peaks of LiClO(4) show 10 wt.% has the highest amount of free ions, in line with the highest conductivity achieved. Finally, the PUA GPE was printed into 3D complex structure to show SLA flexibility in designing an electrolyte, which could be a potential application in advanced battery fabrication. MDPI 2022-09-15 /pmc/articles/PMC9498718/ /pubmed/36135301 http://dx.doi.org/10.3390/gels8090589 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Norjeli, Muhammad Faishal Tamchek, Nizam Osman, Zurina Mohd Noor, Ikhwan Syafiq Kufian, Mohd Zieauddin Ghazali, Mohd Ifwat Bin Mohd Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application |
title | Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application |
title_full | Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application |
title_fullStr | Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application |
title_full_unstemmed | Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application |
title_short | Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application |
title_sort | additive manufacturing polyurethane acrylate via stereolithography for 3d structure polymer electrolyte application |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9498718/ https://www.ncbi.nlm.nih.gov/pubmed/36135301 http://dx.doi.org/10.3390/gels8090589 |
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