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Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application

Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE)....

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Autores principales: Norjeli, Muhammad Faishal, Tamchek, Nizam, Osman, Zurina, Mohd Noor, Ikhwan Syafiq, Kufian, Mohd Zieauddin, Ghazali, Mohd Ifwat Bin Mohd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9498718/
https://www.ncbi.nlm.nih.gov/pubmed/36135301
http://dx.doi.org/10.3390/gels8090589
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author Norjeli, Muhammad Faishal
Tamchek, Nizam
Osman, Zurina
Mohd Noor, Ikhwan Syafiq
Kufian, Mohd Zieauddin
Ghazali, Mohd Ifwat Bin Mohd
author_facet Norjeli, Muhammad Faishal
Tamchek, Nizam
Osman, Zurina
Mohd Noor, Ikhwan Syafiq
Kufian, Mohd Zieauddin
Ghazali, Mohd Ifwat Bin Mohd
author_sort Norjeli, Muhammad Faishal
collection PubMed
description Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE). The printed PUA GPE was then characterized through several techniques, such as Fourier transform infrared (FTIR), electrochemical impedance spectroscopy (EIS), X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The printed GPE exhibited high ionic conductivity of 1.24 × 10(−3) S cm(−1) at low-lithium-salt content (10 wt.%) in ambient temperature and favorable thermal stability to about 300 °C. The FTIR results show that addition of LiClO(4) to the polymer matrix caused a shift in carbonyl, ester and amide functional groups. In addition, FTIR deconvolution peaks of LiClO(4) show 10 wt.% has the highest amount of free ions, in line with the highest conductivity achieved. Finally, the PUA GPE was printed into 3D complex structure to show SLA flexibility in designing an electrolyte, which could be a potential application in advanced battery fabrication.
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spelling pubmed-94987182022-09-23 Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application Norjeli, Muhammad Faishal Tamchek, Nizam Osman, Zurina Mohd Noor, Ikhwan Syafiq Kufian, Mohd Zieauddin Ghazali, Mohd Ifwat Bin Mohd Gels Article Additive manufacturing (AM), also known as 3D-printing technology, is currently integrated in many fields as it possesses an attractive fabrication process. In this work, we deployed the 3D-print stereolithography (SLA) method to print polyurethane acrylate (PUA)-based gel polymer electrolyte (GPE). The printed PUA GPE was then characterized through several techniques, such as Fourier transform infrared (FTIR), electrochemical impedance spectroscopy (EIS), X-ray diffraction analysis (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The printed GPE exhibited high ionic conductivity of 1.24 × 10(−3) S cm(−1) at low-lithium-salt content (10 wt.%) in ambient temperature and favorable thermal stability to about 300 °C. The FTIR results show that addition of LiClO(4) to the polymer matrix caused a shift in carbonyl, ester and amide functional groups. In addition, FTIR deconvolution peaks of LiClO(4) show 10 wt.% has the highest amount of free ions, in line with the highest conductivity achieved. Finally, the PUA GPE was printed into 3D complex structure to show SLA flexibility in designing an electrolyte, which could be a potential application in advanced battery fabrication. MDPI 2022-09-15 /pmc/articles/PMC9498718/ /pubmed/36135301 http://dx.doi.org/10.3390/gels8090589 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Norjeli, Muhammad Faishal
Tamchek, Nizam
Osman, Zurina
Mohd Noor, Ikhwan Syafiq
Kufian, Mohd Zieauddin
Ghazali, Mohd Ifwat Bin Mohd
Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
title Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
title_full Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
title_fullStr Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
title_full_unstemmed Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
title_short Additive Manufacturing Polyurethane Acrylate via Stereolithography for 3D Structure Polymer Electrolyte Application
title_sort additive manufacturing polyurethane acrylate via stereolithography for 3d structure polymer electrolyte application
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9498718/
https://www.ncbi.nlm.nih.gov/pubmed/36135301
http://dx.doi.org/10.3390/gels8090589
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