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Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste

The aim of this study was to optimize the composition of enamel consisting of aluminum pigment and polyphenylsiloxane polymer, in order to achieve the maximum aggregative stability of suspensions. Sedimentation rate (SR) was used as a criterion for assessing the aggregative stability of the suspensi...

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Autores principales: Tyukanko, Vitaliy, Demyanenko, Alexandr, Dyuryagina, Antonina, Ostrovnoy, Kirill, Aubakirova, Gulsim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500862/
https://www.ncbi.nlm.nih.gov/pubmed/36145964
http://dx.doi.org/10.3390/polym14183819
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author Tyukanko, Vitaliy
Demyanenko, Alexandr
Dyuryagina, Antonina
Ostrovnoy, Kirill
Aubakirova, Gulsim
author_facet Tyukanko, Vitaliy
Demyanenko, Alexandr
Dyuryagina, Antonina
Ostrovnoy, Kirill
Aubakirova, Gulsim
author_sort Tyukanko, Vitaliy
collection PubMed
description The aim of this study was to optimize the composition of enamel consisting of aluminum pigment and polyphenylsiloxane polymer, in order to achieve the maximum aggregative stability of suspensions. Sedimentation rate (SR) was used as a criterion for assessing the aggregative stability of the suspensions. An original product, AS-1, and industrial additives PEPA and Telaz, were tested as surfactants. AS-1 was obtained from oil refining waste at M. Kozybayev North Kazakhstan University. All the studied surfactants improved the stability of the suspensions. The AS-1 additive significantly improved the stability of the suspensions, but exhibited a lower stabilizing ability by 10–20% than PEPA. The maximum overall stability of the suspensions was recorded at a PEPA level of 0.25–0.375 g/dm(3) in the enamel. The Taguchi method was used to optimize the composition of the enamel, using AS-1 as the surfactant. It is recommended to use AS-1 in silicone enamels. Optimum compositions can reduce the petrol absorption of coatings by 1.5 times, their roughness by 2.5 times and increase their gloss.
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spelling pubmed-95008622022-09-24 Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste Tyukanko, Vitaliy Demyanenko, Alexandr Dyuryagina, Antonina Ostrovnoy, Kirill Aubakirova, Gulsim Polymers (Basel) Article The aim of this study was to optimize the composition of enamel consisting of aluminum pigment and polyphenylsiloxane polymer, in order to achieve the maximum aggregative stability of suspensions. Sedimentation rate (SR) was used as a criterion for assessing the aggregative stability of the suspensions. An original product, AS-1, and industrial additives PEPA and Telaz, were tested as surfactants. AS-1 was obtained from oil refining waste at M. Kozybayev North Kazakhstan University. All the studied surfactants improved the stability of the suspensions. The AS-1 additive significantly improved the stability of the suspensions, but exhibited a lower stabilizing ability by 10–20% than PEPA. The maximum overall stability of the suspensions was recorded at a PEPA level of 0.25–0.375 g/dm(3) in the enamel. The Taguchi method was used to optimize the composition of the enamel, using AS-1 as the surfactant. It is recommended to use AS-1 in silicone enamels. Optimum compositions can reduce the petrol absorption of coatings by 1.5 times, their roughness by 2.5 times and increase their gloss. MDPI 2022-09-13 /pmc/articles/PMC9500862/ /pubmed/36145964 http://dx.doi.org/10.3390/polym14183819 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tyukanko, Vitaliy
Demyanenko, Alexandr
Dyuryagina, Antonina
Ostrovnoy, Kirill
Aubakirova, Gulsim
Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
title Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
title_full Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
title_fullStr Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
title_full_unstemmed Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
title_short Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
title_sort optimizing the composition of silicone enamel to ensure maximum aggregative stability of its suspensions using surfactant obtained from oil refining waste
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500862/
https://www.ncbi.nlm.nih.gov/pubmed/36145964
http://dx.doi.org/10.3390/polym14183819
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