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Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste
The aim of this study was to optimize the composition of enamel consisting of aluminum pigment and polyphenylsiloxane polymer, in order to achieve the maximum aggregative stability of suspensions. Sedimentation rate (SR) was used as a criterion for assessing the aggregative stability of the suspensi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500862/ https://www.ncbi.nlm.nih.gov/pubmed/36145964 http://dx.doi.org/10.3390/polym14183819 |
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author | Tyukanko, Vitaliy Demyanenko, Alexandr Dyuryagina, Antonina Ostrovnoy, Kirill Aubakirova, Gulsim |
author_facet | Tyukanko, Vitaliy Demyanenko, Alexandr Dyuryagina, Antonina Ostrovnoy, Kirill Aubakirova, Gulsim |
author_sort | Tyukanko, Vitaliy |
collection | PubMed |
description | The aim of this study was to optimize the composition of enamel consisting of aluminum pigment and polyphenylsiloxane polymer, in order to achieve the maximum aggregative stability of suspensions. Sedimentation rate (SR) was used as a criterion for assessing the aggregative stability of the suspensions. An original product, AS-1, and industrial additives PEPA and Telaz, were tested as surfactants. AS-1 was obtained from oil refining waste at M. Kozybayev North Kazakhstan University. All the studied surfactants improved the stability of the suspensions. The AS-1 additive significantly improved the stability of the suspensions, but exhibited a lower stabilizing ability by 10–20% than PEPA. The maximum overall stability of the suspensions was recorded at a PEPA level of 0.25–0.375 g/dm(3) in the enamel. The Taguchi method was used to optimize the composition of the enamel, using AS-1 as the surfactant. It is recommended to use AS-1 in silicone enamels. Optimum compositions can reduce the petrol absorption of coatings by 1.5 times, their roughness by 2.5 times and increase their gloss. |
format | Online Article Text |
id | pubmed-9500862 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-95008622022-09-24 Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste Tyukanko, Vitaliy Demyanenko, Alexandr Dyuryagina, Antonina Ostrovnoy, Kirill Aubakirova, Gulsim Polymers (Basel) Article The aim of this study was to optimize the composition of enamel consisting of aluminum pigment and polyphenylsiloxane polymer, in order to achieve the maximum aggregative stability of suspensions. Sedimentation rate (SR) was used as a criterion for assessing the aggregative stability of the suspensions. An original product, AS-1, and industrial additives PEPA and Telaz, were tested as surfactants. AS-1 was obtained from oil refining waste at M. Kozybayev North Kazakhstan University. All the studied surfactants improved the stability of the suspensions. The AS-1 additive significantly improved the stability of the suspensions, but exhibited a lower stabilizing ability by 10–20% than PEPA. The maximum overall stability of the suspensions was recorded at a PEPA level of 0.25–0.375 g/dm(3) in the enamel. The Taguchi method was used to optimize the composition of the enamel, using AS-1 as the surfactant. It is recommended to use AS-1 in silicone enamels. Optimum compositions can reduce the petrol absorption of coatings by 1.5 times, their roughness by 2.5 times and increase their gloss. MDPI 2022-09-13 /pmc/articles/PMC9500862/ /pubmed/36145964 http://dx.doi.org/10.3390/polym14183819 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Tyukanko, Vitaliy Demyanenko, Alexandr Dyuryagina, Antonina Ostrovnoy, Kirill Aubakirova, Gulsim Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste |
title | Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste |
title_full | Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste |
title_fullStr | Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste |
title_full_unstemmed | Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste |
title_short | Optimizing the Composition of Silicone Enamel to Ensure Maximum Aggregative Stability of Its Suspensions Using Surfactant Obtained from Oil Refining Waste |
title_sort | optimizing the composition of silicone enamel to ensure maximum aggregative stability of its suspensions using surfactant obtained from oil refining waste |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500862/ https://www.ncbi.nlm.nih.gov/pubmed/36145964 http://dx.doi.org/10.3390/polym14183819 |
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