Observation and Analysis of Staircase Response of Single Palladium Nanoparticle Collision on Gold Ultramicroelectrodes

Collision (or impact) of single palladium nanoparticles (Pd NPs) on gold (Au), copper (Cu), nickel (Ni), and platinum (Pt) ultramicroelectrodes (UMEs) were investigated via electrocatalytic amplification method. Unlike the blip responses of previous Pd NP collision studies, the staircase current res...

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Detalles Bibliográficos
Autores principales: Rudakemwa, Hubert, Kim, Ki Jun, Park, Tae Eun, Son, Hyeryeon, Na, Jaedo, Kwon, Seong Jung
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500959/
https://www.ncbi.nlm.nih.gov/pubmed/36144883
http://dx.doi.org/10.3390/nano12183095
Descripción
Sumario:Collision (or impact) of single palladium nanoparticles (Pd NPs) on gold (Au), copper (Cu), nickel (Ni), and platinum (Pt) ultramicroelectrodes (UMEs) were investigated via electrocatalytic amplification method. Unlike the blip responses of previous Pd NP collision studies, the staircase current response was obtained with the Au UME. The current response, including collision frequency and peak magnitude, was analyzed depending on the material of the UME and the applied potential. Adsorption factors implying the interaction between the Pd NP and the UMEs are suggested based on the experimental results.

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