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Visible light induced RAFT for asymmetric functionalization of silica mesopores

One key feature for bioinspired transport design through nanoscale pores is nanolocal, asymmetric as well as multifunctional nanopore functionalization. Here, we use a visible-light induced, controlled photo electron/energy transfer-reversible addition–fragmentation chain-transfer (PET-RAFT) polymer...

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Detalles Bibliográficos
Autores principales: Förster, Claire, Veith, Lothar, Andrieu-Brunsen, Annette
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9501659/
https://www.ncbi.nlm.nih.gov/pubmed/36276013
http://dx.doi.org/10.1039/d2ra05422a
Descripción
Sumario:One key feature for bioinspired transport design through nanoscale pores is nanolocal, asymmetric as well as multifunctional nanopore functionalization. Here, we use a visible-light induced, controlled photo electron/energy transfer-reversible addition–fragmentation chain-transfer (PET-RAFT) polymerization for asymmetric polymer placement into mesoporous silica thin films including asymmetric polymer sequence design.