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Cyclopropane-Fused N-Heterocycles via Aza-Heck-Triggered C(sp(3))–H Functionalization Cascades

[Image: see text] Unique examples of aza-Heck-based C(sp(3))–H functionalization cascades are described. Under Pd(0)-catalyzed conditions, the aza-Heck-type cyclization of N-(pentafluorobenzoyloxy)carbamates generates alkyl–Pd(II) intermediates that effect C(sp(3))–H palladation en route to cyclopro...

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Detalles Bibliográficos
Autores principales:	Jing, Changcheng, Jones, Benjamin T., Adams, Ross J., Bower, John F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9501755/ https://www.ncbi.nlm.nih.gov/pubmed/36083505 http://dx.doi.org/10.1021/jacs.2c08304

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