Cargando…

Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors

In this study, the percolation inception, actual filler amount, and concentration of nets are expressed using the filler size and agglomeration, interphase depth, and tunneling size. A modified form of the power-law model is recommended for the conductivity of graphene–polymer products using the men...

Descripción completa

Detalles Bibliográficos
Autores principales: Zare, Yasser, Rhee, Kyong Yop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9503359/
https://www.ncbi.nlm.nih.gov/pubmed/36143615
http://dx.doi.org/10.3390/ma15186303
_version_ 1784795943492648960
author Zare, Yasser
Rhee, Kyong Yop
author_facet Zare, Yasser
Rhee, Kyong Yop
author_sort Zare, Yasser
collection PubMed
description In this study, the percolation inception, actual filler amount, and concentration of nets are expressed using the filler size and agglomeration, interphase depth, and tunneling size. A modified form of the power-law model is recommended for the conductivity of graphene–polymer products using the mentioned characteristics. The modified model is used to plot and evaluate the conductivity at dissimilar ranges of factors. In addition, the prediction results of the model are compared with the experimented values of several samples. A low percolation inception and high-volume portion of nets that improve the conductivity of nanoparticles are achieved at a low agglomeration extent, thick interphase, large aspect ratio of the nanosheets, and large tunnels. The developed equation for percolation inception accurately predicts the results assuming tunneling and interphase parts. The innovative model predicts the conductivity for the samples, demonstrating good agreement with the experimented values. This model is appropriate to improve breast cancer biosensors, because conductivity plays a key role in sensing.
format Online
Article
Text
id pubmed-9503359
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-95033592022-09-24 Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors Zare, Yasser Rhee, Kyong Yop Materials (Basel) Article In this study, the percolation inception, actual filler amount, and concentration of nets are expressed using the filler size and agglomeration, interphase depth, and tunneling size. A modified form of the power-law model is recommended for the conductivity of graphene–polymer products using the mentioned characteristics. The modified model is used to plot and evaluate the conductivity at dissimilar ranges of factors. In addition, the prediction results of the model are compared with the experimented values of several samples. A low percolation inception and high-volume portion of nets that improve the conductivity of nanoparticles are achieved at a low agglomeration extent, thick interphase, large aspect ratio of the nanosheets, and large tunnels. The developed equation for percolation inception accurately predicts the results assuming tunneling and interphase parts. The innovative model predicts the conductivity for the samples, demonstrating good agreement with the experimented values. This model is appropriate to improve breast cancer biosensors, because conductivity plays a key role in sensing. MDPI 2022-09-11 /pmc/articles/PMC9503359/ /pubmed/36143615 http://dx.doi.org/10.3390/ma15186303 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zare, Yasser
Rhee, Kyong Yop
Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors
title Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors
title_full Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors
title_fullStr Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors
title_full_unstemmed Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors
title_short Modeling of Electrical Conductivity for Graphene-Filled Products Assuming Interphase, Tunneling Effect, and Filler Agglomeration Optimizing Breast Cancer Biosensors
title_sort modeling of electrical conductivity for graphene-filled products assuming interphase, tunneling effect, and filler agglomeration optimizing breast cancer biosensors
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9503359/
https://www.ncbi.nlm.nih.gov/pubmed/36143615
http://dx.doi.org/10.3390/ma15186303
work_keys_str_mv AT zareyasser modelingofelectricalconductivityforgraphenefilledproductsassuminginterphasetunnelingeffectandfilleragglomerationoptimizingbreastcancerbiosensors
AT rheekyongyop modelingofelectricalconductivityforgraphenefilledproductsassuminginterphasetunnelingeffectandfilleragglomerationoptimizingbreastcancerbiosensors