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Design and Synthesis of Pyrrolidinyl Ferrocene-Containing Ligands and Their Application in Highly Enantioselective Rhodium-Catalyzed Olefin Hydrogenation

Herein, we report the design and synthesis of a series of chiral pyrrolidine-substituted ferrocene-derived ligands. The proficiency of this novel structural motif was demonstrated in the Rh-catalyzed asymmetric hydrogenation of dehydroamino acid esters and α-aryl enamides. The products were obtained...

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Detalles Bibliográficos
Autores principales:	Li, Xin, Brennan, Therese B., Kingston, Cian, Ortin, Yannick, Guiry, Patrick J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9505515/ https://www.ncbi.nlm.nih.gov/pubmed/36144811 http://dx.doi.org/10.3390/molecules27186078

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