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A Stable Hexaazaoctacene Cruciform σ‐Dimer

Buchwald‐Hartwig coupling of a triisopropylsilyl (TIPS)‐ethynylated dibromo‐N,N'‐dihydrotetraazapentacene with 1,4‐bis(TIPS‐ethynyl)‐2,3‐diaminonaphthalene furnishes a dihydrohexaazaoctacene. Its oxidation with MnO(2) results in a 7,7'‐bi(hexaazaoctacenyl). In addition to eight TIPS‐ethyny...

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Detalles Bibliográficos
Autores principales: Maier, Steffen, Jester, Fabian, Hoffmann, Marvin T., Rominger, Frank, Freudenberg, Jan, Dreuw, Andreas, Bunz, Uwe H. F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9507379/
https://www.ncbi.nlm.nih.gov/pubmed/35896771
http://dx.doi.org/10.1002/advs.202202710