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Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?

[Image: see text] The use of carbon nanotubes (CNTs) as electrocatalysts is summarized; the limitations of using voltammetry based on CNT-modified electrodes is explained; and the role of mass transport, as well as electrode kinetics, with respect to dictating the voltammetric responses is discussed...

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Autores principales: Kaliyaraj Selva Kumar, Archana, Lu, Yuanyuan, Compton, Richard G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9511562/
https://www.ncbi.nlm.nih.gov/pubmed/36094419
http://dx.doi.org/10.1021/acs.jpclett.2c02464
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author Kaliyaraj Selva Kumar, Archana
Lu, Yuanyuan
Compton, Richard G.
author_facet Kaliyaraj Selva Kumar, Archana
Lu, Yuanyuan
Compton, Richard G.
author_sort Kaliyaraj Selva Kumar, Archana
collection PubMed
description [Image: see text] The use of carbon nanotubes (CNTs) as electrocatalysts is summarized; the limitations of using voltammetry based on CNT-modified electrodes is explained; and the role of mass transport, as well as electrode kinetics, with respect to dictating the voltammetric responses is discussed. The use of single-entity electrochemistry to at least complement, if not replace, ensemble voltammetry is advocated along with other caveats, notably purity, with respect to CNT voltammetry.
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spelling pubmed-95115622022-09-27 Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic? Kaliyaraj Selva Kumar, Archana Lu, Yuanyuan Compton, Richard G. J Phys Chem Lett [Image: see text] The use of carbon nanotubes (CNTs) as electrocatalysts is summarized; the limitations of using voltammetry based on CNT-modified electrodes is explained; and the role of mass transport, as well as electrode kinetics, with respect to dictating the voltammetric responses is discussed. The use of single-entity electrochemistry to at least complement, if not replace, ensemble voltammetry is advocated along with other caveats, notably purity, with respect to CNT voltammetry. American Chemical Society 2022-09-12 2022-09-22 /pmc/articles/PMC9511562/ /pubmed/36094419 http://dx.doi.org/10.1021/acs.jpclett.2c02464 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Kaliyaraj Selva Kumar, Archana
Lu, Yuanyuan
Compton, Richard G.
Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?
title Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?
title_full Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?
title_fullStr Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?
title_full_unstemmed Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?
title_short Voltammetry of Carbon Nanotubes and the Limitations of Particle-Modified Electrodes: Are Carbon Nanotubes Electrocatalytic?
title_sort voltammetry of carbon nanotubes and the limitations of particle-modified electrodes: are carbon nanotubes electrocatalytic?
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9511562/
https://www.ncbi.nlm.nih.gov/pubmed/36094419
http://dx.doi.org/10.1021/acs.jpclett.2c02464
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