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Organocatalytic Enantioselective γ-Position-Selective Mannich Reactions of β-Ketocarbonyl Derivatives

[Image: see text] Catalytic asymmetric Mannich reactions of β-ketocarbonyl derivatives (such as β-ketoesters and (2-oxopropyl)phosphonate), resulting in the formation of a C–C bond at the γ-position of the β-ketocarbonyl derivatives with high enantioselectivities, are reported. The bond formation at...

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Detalles Bibliográficos
Autores principales: Bethi, Venkati, Tanaka, Fujie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9513800/
https://www.ncbi.nlm.nih.gov/pubmed/36096488
http://dx.doi.org/10.1021/acs.orglett.2c02433

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