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Utilising problematic waste to detect toxic gas release in the environment: fabricating a NiO doped CuO nanoflake based ammonia sensor from e-waste

Using problematic electronic waste to synthesise high-purity nanomaterials can enable sustainable production and create opportunities to divert waste from landfills. Reported here is a simple strategy for the controllable synthesis of in situ NiO doped CuO nanoflakes from waste flexible printed circ...

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Detalles Bibliográficos
Autores principales: Hossain, Rumana, Hassan, Kamrul, Sahajwalla, Veena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: RSC 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9514563/
https://www.ncbi.nlm.nih.gov/pubmed/36285214
http://dx.doi.org/10.1039/d1na00743b
Descripción
Sumario:Using problematic electronic waste to synthesise high-purity nanomaterials can enable sustainable production and create opportunities to divert waste from landfills. Reported here is a simple strategy for the controllable synthesis of in situ NiO doped CuO nanoflakes from waste flexible printed circuit boards (FPCBs) using a chemothermal microrecycling process, and the nanomaterial is then utilised for an ammonia (NH(3)) sensor at room temperature. Characterisation of the nanoflakes confirmed the purity of the CuO phase with a monoclinic structure without the formation of the Cu(2)O phase. The NiO doped CuO 2D nanoflakes made of an assembly of 1D nanorods with a high surface area of 115.703 m(2) g(−1) are selectively synthesised from the waste FPCBs and have outstanding gas sensing characteristics such as a high response, a fast response (11.7 s) and a recovery time of (21.5 s), good stability, and superior selectivity towards 200 ppm of NH(3) gas at room temperature (RT, 20 °C). From a broader perspective, the process opens up exciting new avenues explore the production of toxic gas sensing functional materials from toxic and problematic waste.