Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides

In this research, a simple, efficient and novel protocol is eveloped for the direct synthesis of symmetrical disulfides using dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new, low toxicity, inexpensive, stable solid and free of foul-smelling thiols for synthesize symmetric diaryl/dialkyl dis...

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Autores principales: Soleiman-Beigi, Mohammad, Alikarami, Mohammad, Kohzadi, Homa, Akbari, Zahra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9515069/
https://www.ncbi.nlm.nih.gov/pubmed/36167798
http://dx.doi.org/10.1038/s41598-022-20642-5
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author Soleiman-Beigi, Mohammad
Alikarami, Mohammad
Kohzadi, Homa
Akbari, Zahra
author_facet Soleiman-Beigi, Mohammad
Alikarami, Mohammad
Kohzadi, Homa
Akbari, Zahra
author_sort Soleiman-Beigi, Mohammad
collection PubMed
description In this research, a simple, efficient and novel protocol is eveloped for the direct synthesis of symmetrical disulfides using dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new, low toxicity, inexpensive, stable solid and free of foul-smelling thiols for synthesize symmetric diaryl/dialkyl disulfides from aryl and alkyl halides in presence of MOF-199 and CuO nanoparticles. Significantly, using this method results in obtaining a variety of symmetrical disulfides in moderate to excellent yields (up to 98%).
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spelling pubmed-95150692022-09-29 Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides Soleiman-Beigi, Mohammad Alikarami, Mohammad Kohzadi, Homa Akbari, Zahra Sci Rep Article In this research, a simple, efficient and novel protocol is eveloped for the direct synthesis of symmetrical disulfides using dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new, low toxicity, inexpensive, stable solid and free of foul-smelling thiols for synthesize symmetric diaryl/dialkyl disulfides from aryl and alkyl halides in presence of MOF-199 and CuO nanoparticles. Significantly, using this method results in obtaining a variety of symmetrical disulfides in moderate to excellent yields (up to 98%). Nature Publishing Group UK 2022-09-27 /pmc/articles/PMC9515069/ /pubmed/36167798 http://dx.doi.org/10.1038/s41598-022-20642-5 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Soleiman-Beigi, Mohammad
Alikarami, Mohammad
Kohzadi, Homa
Akbari, Zahra
Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
title Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
title_full Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
title_fullStr Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
title_full_unstemmed Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
title_short Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
title_sort dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new s-donor for direct synthesis of symmetrical disulfides
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9515069/
https://www.ncbi.nlm.nih.gov/pubmed/36167798
http://dx.doi.org/10.1038/s41598-022-20642-5
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