Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N–O Bond Cleavage Reactions

[Image: see text] The novel nitrosyl-bridged complex [W(2)Cp(2)(μ-P(t)Bu(2))(μ-κ:η-NO)(CO)(NO)](BAr(4)) [Ar = 3,5-C(6)H(3)(CF(3))(2)] was prepared in a multistep procedure starting from the hydride [W(2)Cp(2)(μ-H)(μ-P(t)Bu(2))(CO)(4)] and involving the new complexes [W(2)Cp(2)(μ-P(t)Bu(2))(CO)(4)](B...

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Detalles Bibliográficos
Autores principales: Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Guerra, Ana M., Ruiz, Miguel A., Falvello, Larry R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516685/
https://www.ncbi.nlm.nih.gov/pubmed/36106823
http://dx.doi.org/10.1021/acs.inorgchem.2c02216

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516685/
https://www.ncbi.nlm.nih.gov/pubmed/36106823
http://dx.doi.org/10.1021/acs.inorgchem.2c02216

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