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Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N–O Bond Cleavage Reactions
[Image: see text] The novel nitrosyl-bridged complex [W(2)Cp(2)(μ-P(t)Bu(2))(μ-κ:η-NO)(CO)(NO)](BAr(4)) [Ar = 3,5-C(6)H(3)(CF(3))(2)] was prepared in a multistep procedure starting from the hydride [W(2)Cp(2)(μ-H)(μ-P(t)Bu(2))(CO)(4)] and involving the new complexes [W(2)Cp(2)(μ-P(t)Bu(2))(CO)(4)](B...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516685/ https://www.ncbi.nlm.nih.gov/pubmed/36106823 http://dx.doi.org/10.1021/acs.inorgchem.2c02216 |