Atom and step economical synthesis of acyclic quaternary centers via iridium-catalyzed hydroarylative cross-coupling of 1,1-disubstituted alkenes

Quaternary benzylic centers are accessed with high atom and step economy by Ir-catalyzed alkene hydroarylation. These studies provide unique examples of the use of non-polarized 1,1-disubstituted alkenes in branch selective Murai-type hydro(hetero)arylations. Detailed mechanistic studies have been u...

Descripción completa

Detalles Bibliográficos
Autores principales: Cooper, Phillippa, Dalling, Andrew G., Farrar, Elliot H. E., Aldhous, Timothy P., Grélaud, Simon, Lester, Eleanor, Feron, Lyman J., Kemmitt, Paul D., Grayson, Matthew N., Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516889/
https://www.ncbi.nlm.nih.gov/pubmed/36320466
http://dx.doi.org/10.1039/d2sc02790a

Ejemplares similares

Ejemplares similares