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Calix[4]pyrrolato gallate: square planar-coordinated gallium(iii) and its metal–ligand cooperative reactivity with CO(2) and alcohols

Forcing a priori tetracoordinate atoms into planar configuration represents a promising concept for enhanced reactivity of p-block element-based systems. Herein, the synthesis, characterization, and reactivity of calix[4]pyrrolato gallates, constituting square planar-coordinated gallium(iii) atoms,...

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Detalles Bibliográficos
Autores principales: Sigmund, Lukas M., Engels, Eliane, Richert, Nick, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516954/
https://www.ncbi.nlm.nih.gov/pubmed/36320463
http://dx.doi.org/10.1039/d2sc03054c