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Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect

This review aims at providing an overview of the most significant applications of fluorine-containing ligands reported in the literature starting from 2001 until mid-2021. The ligands are classified according to the nature of the donor atoms involved. This review highlights both metal–ligand interac...

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Detalles Bibliográficos
Autores principales: Lauzon, Samuel, Ollevier, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516955/
https://www.ncbi.nlm.nih.gov/pubmed/36320478
http://dx.doi.org/10.1039/d2sc01096h
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author Lauzon, Samuel
Ollevier, Thierry
author_facet Lauzon, Samuel
Ollevier, Thierry
author_sort Lauzon, Samuel
collection PubMed
description This review aims at providing an overview of the most significant applications of fluorine-containing ligands reported in the literature starting from 2001 until mid-2021. The ligands are classified according to the nature of the donor atoms involved. This review highlights both metal–ligand interactions and the structure–reactivity relationships resulting from the presence of the fluorine atom or fluorine-containing substituents on chiral catalysts.
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spelling pubmed-95169552022-10-31 Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect Lauzon, Samuel Ollevier, Thierry Chem Sci Chemistry This review aims at providing an overview of the most significant applications of fluorine-containing ligands reported in the literature starting from 2001 until mid-2021. The ligands are classified according to the nature of the donor atoms involved. This review highlights both metal–ligand interactions and the structure–reactivity relationships resulting from the presence of the fluorine atom or fluorine-containing substituents on chiral catalysts. The Royal Society of Chemistry 2022-08-08 /pmc/articles/PMC9516955/ /pubmed/36320478 http://dx.doi.org/10.1039/d2sc01096h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Lauzon, Samuel
Ollevier, Thierry
Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
title Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
title_full Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
title_fullStr Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
title_full_unstemmed Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
title_short Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
title_sort fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516955/
https://www.ncbi.nlm.nih.gov/pubmed/36320478
http://dx.doi.org/10.1039/d2sc01096h
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