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Reconstructing reactivity in dynamic host–guest systems at atomistic resolution: amide hydrolysis under confinement in the cavity of a coordination cage

Spatial confinement is widely employed by nature to attain unique efficiency in controlling chemical reactions. Notable examples are enzymes, which selectively bind reactants and exquisitely regulate their conversion into products. In an attempt to mimic natural catalytic systems, supramolecular met...

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Detalles Bibliográficos
Autores principales: Delle Piane, Massimo, Pesce, Luca, Cioni, Matteo, Pavan, Giovanni M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9517058/
https://www.ncbi.nlm.nih.gov/pubmed/36320487
http://dx.doi.org/10.1039/d2sc02000a