Structural Characteristics and Electrochemical Performance of N,P-Codoped Porous Carbon as a Lithium-Ion Battery Anode Electrode

[Image: see text] Biomass-derived heteroatom-doped carbons have been considered to be excellent lithium ion battery (LIB) anode materials. Herein, ultrathin g-C(3)N(4) nanosheets anchored on N,P-codoped biomass-derived carbon (N,P@C) were successfully fabricated by carbonization in an argon atmosphere. The structural characteristics of the resultant N,P@C were elucidated by SEM, TEM, FTIR, XRD, XPS, Raman, and BET surface area measurements. The results show that N,P@C has a high specific surface area (S(BET) = 675.4 cm(3)/g), a mesoporous-dominant pore (average pore size of 6.898 nm), and a high level of defects (I(D)/I(G) = 1.02). The hierarchical porous structural properties are responsible for the efficient electrochemical performance of N,P@C as an anode material, which exhibits an outstanding reversible specific capacity of 1264.3 mAh/g at 100 mA/g, an elegant rate capability of 261 mAh/g at 10 A, and a satisfactory cycling stability of 1463.8 mAh/g at 1 A after 500 cycles. Because of the special structure and synergistic contributions from N and P heteroatoms, the resultant N,P@C endows LIBs with electrochemical performance superior to those of most of carbon-based anode materials derived from biomass in the literature. The findings in this present work pave a novel avenue toward lignin volarization to produce anode material for use in high-performance LIBs.