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Recent Progress in Aqueous Ammonium-Ion Batteries

[Image: see text] Batteries using a water-based electrolyte have the potential to be safer, more durable, less prone to thermal runaways, and less costly than current lithium batteries using an organic solvent. Among the possible aqueous battery options, ammonium-ion batteries (AIBs) are very appeal...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Kuchena, Shelton F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9520733/
https://www.ncbi.nlm.nih.gov/pubmed/36188297
http://dx.doi.org/10.1021/acsomega.2c04118
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author Wang, Ying
Kuchena, Shelton F.
author_facet Wang, Ying
Kuchena, Shelton F.
author_sort Wang, Ying
collection PubMed
description [Image: see text] Batteries using a water-based electrolyte have the potential to be safer, more durable, less prone to thermal runaways, and less costly than current lithium batteries using an organic solvent. Among the possible aqueous battery options, ammonium-ion batteries (AIBs) are very appealing because the base materials are light, safe, inexpensive, and widely available. This review gives a concise and useful survey of recent progress on emerging AIBs, starting with a brief overview of AIBs, followed by cathode materials, anode materials, electrolytes, and various devices based on ammonium-ion storage. Aside from summarizing the most updated electrodes/electrolytes in AIBs, this review highlights fundamental mechanistic studies in AIBs and state-of-the art applications of ammonium-ion storage. The present work reviews various theoretical efforts and the spectrum studies that have been used to explore ionic transport kinetics, electrolyte structure, solvation behavior of ammonium ions, and the intercalation mechanism in the host structure. Furthermore, diverse applications of ammonium-ion storage apart from aqueous AIBs are discussed, including flexible AIBs, AIBs that can operate across a wide temperature range, ammonium-ion supercapacitors, and battery–supercapacitor hybrid devices. Finally, the review is concluded with perspectives of AIBs, challenges remaining in the field, and possible research directions to address these challenges to boost the performance of AIBs for real-world practical applications.
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spelling pubmed-95207332022-09-30 Recent Progress in Aqueous Ammonium-Ion Batteries Wang, Ying Kuchena, Shelton F. ACS Omega [Image: see text] Batteries using a water-based electrolyte have the potential to be safer, more durable, less prone to thermal runaways, and less costly than current lithium batteries using an organic solvent. Among the possible aqueous battery options, ammonium-ion batteries (AIBs) are very appealing because the base materials are light, safe, inexpensive, and widely available. This review gives a concise and useful survey of recent progress on emerging AIBs, starting with a brief overview of AIBs, followed by cathode materials, anode materials, electrolytes, and various devices based on ammonium-ion storage. Aside from summarizing the most updated electrodes/electrolytes in AIBs, this review highlights fundamental mechanistic studies in AIBs and state-of-the art applications of ammonium-ion storage. The present work reviews various theoretical efforts and the spectrum studies that have been used to explore ionic transport kinetics, electrolyte structure, solvation behavior of ammonium ions, and the intercalation mechanism in the host structure. Furthermore, diverse applications of ammonium-ion storage apart from aqueous AIBs are discussed, including flexible AIBs, AIBs that can operate across a wide temperature range, ammonium-ion supercapacitors, and battery–supercapacitor hybrid devices. Finally, the review is concluded with perspectives of AIBs, challenges remaining in the field, and possible research directions to address these challenges to boost the performance of AIBs for real-world practical applications. American Chemical Society 2022-09-13 /pmc/articles/PMC9520733/ /pubmed/36188297 http://dx.doi.org/10.1021/acsomega.2c04118 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Wang, Ying
Kuchena, Shelton F.
Recent Progress in Aqueous Ammonium-Ion Batteries
title Recent Progress in Aqueous Ammonium-Ion Batteries
title_full Recent Progress in Aqueous Ammonium-Ion Batteries
title_fullStr Recent Progress in Aqueous Ammonium-Ion Batteries
title_full_unstemmed Recent Progress in Aqueous Ammonium-Ion Batteries
title_short Recent Progress in Aqueous Ammonium-Ion Batteries
title_sort recent progress in aqueous ammonium-ion batteries
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9520733/
https://www.ncbi.nlm.nih.gov/pubmed/36188297
http://dx.doi.org/10.1021/acsomega.2c04118
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