Enantioselective total synthesis of putative dihydrorosefuran, a monoterpene with an unique 2,5-dihydrofuran structure

An original synthesis of the structure of dihydrorosefuran, a compound allegedly identified in Artemisia pallens and Tagetes mendocina, has been developed. The key steps in the five-step 36% overall yield synthesis are a CpTi(III)Cl(2) mediated Barbier-type allenylation of a linear aldehyde and the...

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Detalles Bibliográficos
Autores principales: Torres-García, Irene, López-Martínez, Josefa L, López-Domene, Rocío, Muñoz-Dorado, Manuel, Rodríguez-García, Ignacio, Álvarez-Corral, Miriam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9520846/
https://www.ncbi.nlm.nih.gov/pubmed/36225730
http://dx.doi.org/10.3762/bjoc.18.132

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9520846/
https://www.ncbi.nlm.nih.gov/pubmed/36225730
http://dx.doi.org/10.3762/bjoc.18.132

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