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Enantioselective total synthesis of putative dihydrorosefuran, a monoterpene with an unique 2,5-dihydrofuran structure

An original synthesis of the structure of dihydrorosefuran, a compound allegedly identified in Artemisia pallens and Tagetes mendocina, has been developed. The key steps in the five-step 36% overall yield synthesis are a CpTi(III)Cl(2) mediated Barbier-type allenylation of a linear aldehyde and the...

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Detalles Bibliográficos
Autores principales:	Torres-García, Irene, López-Martínez, Josefa L, López-Domene, Rocío, Muñoz-Dorado, Manuel, Rodríguez-García, Ignacio, Álvarez-Corral, Miriam
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2022
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9520846/ https://www.ncbi.nlm.nih.gov/pubmed/36225730 http://dx.doi.org/10.3762/bjoc.18.132

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