Harnessing magnetic fields for rare-earth complex crystallization–separations in aqueous solutions

Magnetic field-directed crystallization separation of rare-earth (RE) metals is emerging as a new direction in the field of separation science, due to its simplicity, low energy input, and low cost of operation, as compared to traditional separation methods such as solvent extraction. Here, we report the use of Fe(14)Nd(2)B magnets for selective crystallization of paramagnetic Nd, Dy, Er, and Tm rare earth compounds from a mixture with diamagnetic La ones using the RE–DOTA complex system. All the separations were performed at milder temperatures of 3 °C to provide a thermal gradient, and the crystallizations were set up in aqueous solutions using the benign solvents water and acetone. A four-fold increase in the separation factor (41.4 ± 0.6) was observed for the Dy/La pair in the presence of a magnetic field as compared to the separation factor (10.5 ± 0.9) obtained without the application of the field. These results indicate that the use of the magnetic crystallization method for RE separations is effective in aqueous systems and can be a useful strategy for energy-efficient molecular separations of RE metals.