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Electronic Character of α,3‐Dehydrotoluene Intermediates Generated from Isolable Allenyne‐Containing Substrates
We report here the generation of α,3‐dehydrotoluenes, a relatively rare subset of reactive intermediates of the dehydroaromatic family, from isolable allenynes. The substructure motif in the allenyne substrates is distinct from, and complementary to, those found in Myers‐Saito/Schmittel‐type cyclois...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9529817/ https://www.ncbi.nlm.nih.gov/pubmed/35965409 http://dx.doi.org/10.1002/anie.202207510 |