Cargando…

Synthesis of Sulfur-Substituted Bicyclo[1.1.1]pentanes by Iodo-Sulfenylation of [1.1.1]Propellane

[Image: see text] Thiols easily react with [1.1.1]propellane to give sulfur-substituted bicyclo[1.1.1]pentanes in radical reactions, but this reactivity is not replicated in the case of heterocyclic thiols. Herein, we address this issue by electrophilically activating [1.1.1]propellane to promote it...

Descripción completa

Detalles Bibliográficos
Autores principales: Livesley, Sarah, Trueman, Bethany, Robertson, Craig M., Goundry, William R. F., Morris, James A., Aïssa, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9531248/
https://www.ncbi.nlm.nih.gov/pubmed/36130142
http://dx.doi.org/10.1021/acs.orglett.2c02875