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Unprecedented pairs of uranium (iv/v) hydroxido and (iv/v/vi) oxido complexes supported by a seven-coordinate cyclen-anchored tris-aryloxide ligand
We present the synthesis and reactivity of a newly developed, cyclen-based tris-aryloxide ligand precursor, namely cyclen(Me)((t-Bu,t-Bu)ArOH)(3), and its coordination chemistry to uranium. The corresponding uranium(iii) complex [U(III)((OAr(t-Bu,t-Bu))(3)(Me)cyclen)] (1) was characterized by (1)H N...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9533418/ https://www.ncbi.nlm.nih.gov/pubmed/36320575 http://dx.doi.org/10.1039/d2sc02736d |