[3+2] click chemistry approach to tetrazine containing polymers

We report a [3+2] cycloaddition using 3,6-bis-propargyloxy-1,2,4,5-tetrazine and azides to synthesize energetic polymers containing 1,2,4,5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide p...

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Detalles Bibliográficos
Autores principales: Chavez, David E., Tappan, Bryce C., Kuehl, Valerie A., Schmalzer, Andrew M., Leonard, Philip W., Wu, Ruilian, Imler, Greg H., Parrish, Damon A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535468/
https://www.ncbi.nlm.nih.gov/pubmed/36320529
http://dx.doi.org/10.1039/d2ra05339j
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author Chavez, David E.
Tappan, Bryce C.
Kuehl, Valerie A.
Schmalzer, Andrew M.
Leonard, Philip W.
Wu, Ruilian
Imler, Greg H.
Parrish, Damon A.
author_facet Chavez, David E.
Tappan, Bryce C.
Kuehl, Valerie A.
Schmalzer, Andrew M.
Leonard, Philip W.
Wu, Ruilian
Imler, Greg H.
Parrish, Damon A.
author_sort Chavez, David E.
collection PubMed
description We report a [3+2] cycloaddition using 3,6-bis-propargyloxy-1,2,4,5-tetrazine and azides to synthesize energetic polymers containing 1,2,4,5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide pathways for incorporation of 1,2,4,5-tetrazine into novel energetic materials using click-chemistry and provide an alternative polymer curing approach.
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spelling pubmed-95354682022-10-31 [3+2] click chemistry approach to tetrazine containing polymers Chavez, David E. Tappan, Bryce C. Kuehl, Valerie A. Schmalzer, Andrew M. Leonard, Philip W. Wu, Ruilian Imler, Greg H. Parrish, Damon A. RSC Adv Chemistry We report a [3+2] cycloaddition using 3,6-bis-propargyloxy-1,2,4,5-tetrazine and azides to synthesize energetic polymers containing 1,2,4,5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide pathways for incorporation of 1,2,4,5-tetrazine into novel energetic materials using click-chemistry and provide an alternative polymer curing approach. The Royal Society of Chemistry 2022-10-06 /pmc/articles/PMC9535468/ /pubmed/36320529 http://dx.doi.org/10.1039/d2ra05339j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Chavez, David E.
Tappan, Bryce C.
Kuehl, Valerie A.
Schmalzer, Andrew M.
Leonard, Philip W.
Wu, Ruilian
Imler, Greg H.
Parrish, Damon A.
[3+2] click chemistry approach to tetrazine containing polymers
title [3+2] click chemistry approach to tetrazine containing polymers
title_full [3+2] click chemistry approach to tetrazine containing polymers
title_fullStr [3+2] click chemistry approach to tetrazine containing polymers
title_full_unstemmed [3+2] click chemistry approach to tetrazine containing polymers
title_short [3+2] click chemistry approach to tetrazine containing polymers
title_sort [3+2] click chemistry approach to tetrazine containing polymers
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535468/
https://www.ncbi.nlm.nih.gov/pubmed/36320529
http://dx.doi.org/10.1039/d2ra05339j
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