Crystal structure of MgK(0.5)[B(6)O(10)](OH)(0.5)·0.5H(2)O, poly[dimagnesium potassium bis(hexa­borate) hy­droxide monohydrate]

The solvothermal reaction of H(3)BO(3), KCF(3)SO(3), Mg(CF(3)SO(3))(2) and pyridine led to a new alkali- and alkaline-earth-metal borate, MgK(0.5)[B(6)O(10)](OH)(0.5)·0.5H(2)O. Its structure features an intricate three-dimensional framework built from [B(6)O(13)](8−) clusters, thus resulting in a si...

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Detalles Bibliográficos
Autores principales: Qiu, Qi-Ming, Song, Jian-Biao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535820/
https://www.ncbi.nlm.nih.gov/pubmed/36250118
http://dx.doi.org/10.1107/S2056989022008982
Descripción
Sumario:The solvothermal reaction of H(3)BO(3), KCF(3)SO(3), Mg(CF(3)SO(3))(2) and pyridine led to a new alkali- and alkaline-earth-metal borate, MgK(0.5)[B(6)O(10)](OH)(0.5)·0.5H(2)O. Its structure features an intricate three-dimensional framework built from [B(6)O(13)](8−) clusters, thus resulting in a six-connected achiral net with high symmetry. Each [B(6)O(13)](8−) building block is composed of three trigonal BO(3) and three tetra­hedral BO(4) units, with these BO(4) units being further connected to neighboring BO(3) units, giving rise to an oxoboron cluster of the general formula [B(6)O(10)](2−).

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