The methanol and ethanol solvates of 4-glutarato-N,N-diiso­propyl­tryptamine

The solid-state structures of two solvated forms of 4-glutarato-N,N-diiso­propyl­tryptamine were determined by single-crystal X-ray diffraction, namely, 5-[(3-{2-[bis(propan-2-yl)azaniumyl]ethyl}-1H-indol-4-yl)oxy]-5-oxopentanoate meth­anol monosolvate, C(21)H(30)N(2)O(4)·CH(3)OH, and the analogous ethanol monosolvate, C(21)H(30)N(2)O(4)·C(2)H(6)O. In both compounds, the 4-glutarato-N,N-di­iso­­pro­pyl­tryptamine exists as a zwitterion with a protonated tertiary ammonium and a deprotonated glutarato carboxyl­ate. The tryptamine zwitterions and alcohol solvates in both structures combine to produce near identical hydrogen-bonding networks, with N—H⋯O and O—H⋯O hydrogen bonds joining the mol­ecules together in two-dimensional networks parallel to the (100) plane.