Crystal structure of Rb(6)[B(12)O(18)(OH)(6)]·2H(2)O

The solvothermal reaction of H(3)BO(3), sodium tert-butoxide, Rb(2)CO(3) and pyridine led to a new alkaline metal borate hexa­rubidium hexa­hydroxy­dodeca­borate dihydrate, Rb(6)[B(12)O(18)(OH)(6)]·2H(2)O. Its structure contains a large cyclic dodeca­oxoboron cluster, [B(12)O(18)(OH)(6)](6−), formed...

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Detalles Bibliográficos
Autores principales: Qiu, Qi-Ming, Yan, Li, Song, Jian-Biao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535828/
https://www.ncbi.nlm.nih.gov/pubmed/36250120
http://dx.doi.org/10.1107/S2056989022008611
Descripción
Sumario:The solvothermal reaction of H(3)BO(3), sodium tert-butoxide, Rb(2)CO(3) and pyridine led to a new alkaline metal borate hexa­rubidium hexa­hydroxy­dodeca­borate dihydrate, Rb(6)[B(12)O(18)(OH)(6)]·2H(2)O. Its structure contains a large cyclic dodeca­oxoboron cluster, [B(12)O(18)(OH)(6)](6−), formed by six {B(3)O(3)} rings. In the crystal, O—H⋯O hydrogen bonds between the components lead to the formation of a three-dimensional supra­molecular framework.

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