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Crystal structure of catena-poly[[[bis(1-benzylimidazole-κN)copper(II)]-μ-sulfato-κ(2) O:O′-[tetrakis(1-benzylimidazole-κN)copper(II)]-μ-sulfato-κ(2) O:O′] N,N-dimethylformamide disolvate dihydrate]
The title one-dimensional copper(II) coordination polymer, {[Cu(SO(4))(C(10)H(10)N(2))(3)]·C(3)H(7)NO·H(2)O}( n ) or {[Cu(bzi)(3)(μ-O(2)SO(2))]·H(2)O·DMF}( n ) (bzi = 1-benzylimidazole, C(10)H(10)N(2); DMF = N,N-dimethylformamide, C(3)H(7)NO), is constructed by monodentate bzi ligands and bridgi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535829/ https://www.ncbi.nlm.nih.gov/pubmed/36250111 http://dx.doi.org/10.1107/S2056989022008714 |
Sumario: | The title one-dimensional copper(II) coordination polymer, {[Cu(SO(4))(C(10)H(10)N(2))(3)]·C(3)H(7)NO·H(2)O}( n ) or {[Cu(bzi)(3)(μ-O(2)SO(2))]·H(2)O·DMF}( n ) (bzi = 1-benzylimidazole, C(10)H(10)N(2); DMF = N,N-dimethylformamide, C(3)H(7)NO), is constructed by monodentate bzi ligands and bridging sulfate anions, leading to chains propagating parallel to the c axis. Within a chain, there are two crystallographic independent Cu(II) ions, each with site symmetry [Image: see text] , which form [CuN(2)O(2)] and [CuN(4)O(2)] polyhedra alternating along the chain direction. The crystal structure is consolidated by weak hydrogen-bonding, C—H⋯π and π–π interactions, leading to the formation of a three-dimensional supramolecular network. |
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