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Crystal structure and Hirshfeld surface analysis of 3-({4-[(4-cyano­phen­oxy)carbon­yl]phen­oxy}carbon­yl)phenyl 4-(benz­yloxy)-3-chloro­benzoate

The title compound, C(35)H(22)ClNO(7), is a non-liquid crystal with a bent-shaped mol­ecule. The dihedral angles between adjacent aromatic rings in the mol­ecule (starting from the cyano­benzene ring) are 72.61 (2), 87.69 (4), 64.08 (2) and 88.23 (2)°, indicating that adjacent rings are close to per...

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Detalles Bibliográficos
Autores principales: Selvanandan, S., Anil kumar, H., Srinivasa, H. T., Palakshamurthy, B. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535834/
https://www.ncbi.nlm.nih.gov/pubmed/36250112
http://dx.doi.org/10.1107/S2056989022008441
Descripción
Sumario:The title compound, C(35)H(22)ClNO(7), is a non-liquid crystal with a bent-shaped mol­ecule. The dihedral angles between adjacent aromatic rings in the mol­ecule (starting from the cyano­benzene ring) are 72.61 (2), 87.69 (4), 64.08 (2) and 88.23 (2)°, indicating that adjacent rings are close to perpendicular to each other. In the crystal, the mol­ecules are linked by weak C—H⋯N and C—H⋯π inter­actions, thereby forming a two-dimensional supra­molecular architecture in the ac plane. The most important contributions to the crystal packing arise from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) inter­actions, as determined by a Hirshfeld surface analysis.