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Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride
N-{[Diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary aminomethylsilane that can be used, for example, to study carbolithiation reactions of vinylsilanes. Because the neutral compound did not crystallize well, the hydrochloride salt, C(19...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535837/ https://www.ncbi.nlm.nih.gov/pubmed/36250106 http://dx.doi.org/10.1107/S2056989022009112 |
Sumario: | N-{[Diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary aminomethylsilane that can be used, for example, to study carbolithiation reactions of vinylsilanes. Because the neutral compound did not crystallize well, the hydrochloride salt, C(19)H(26)NSi(+)·Cl(−), was formed, in which the two chloride ions in the asymmetric unit have crystallographic [Image: see text] site symmetry. An unusually long Si—C bond of 1.9117 (10) Å is observed in the cation, which may be ascribed to electronic effects due to the β N(+) species. In the crystal, the cations and anions are linked by N—H⋯Cl hydrogen bonds to generate [001] chains. To further investigate the intermolecular interactions, a Hirshfeld surface analysis was performed, which showed that H⋯H, C⋯H/H⋯C and H⋯Cl/Cl⋯H contacts contribute 70.4, 20.0 and 8.3%, respectively. |
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