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Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride

N-{[Diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary amino­methyl­silane that can be used, for example, to study carboli­thia­tion reactions of vinyl­silanes. Because the neutral compound did not crystallize well, the hydro­chloride salt, C(19...

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Autores principales: Schwab, Christoph, Voss, Andreas, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535837/
https://www.ncbi.nlm.nih.gov/pubmed/36250106
http://dx.doi.org/10.1107/S2056989022009112
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author Schwab, Christoph
Voss, Andreas
Strohmann, Carsten
author_facet Schwab, Christoph
Voss, Andreas
Strohmann, Carsten
author_sort Schwab, Christoph
collection PubMed
description N-{[Diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary amino­methyl­silane that can be used, for example, to study carboli­thia­tion reactions of vinyl­silanes. Because the neutral compound did not crystallize well, the hydro­chloride salt, C(19)H(26)NSi(+)·Cl(−), was formed, in which the two chloride ions in the asymmetric unit have crystallographic [Image: see text] site symmetry. An unusually long Si—C bond of 1.9117 (10) Å is observed in the cation, which may be ascribed to electronic effects due to the β N(+) species. In the crystal, the cations and anions are linked by N—H⋯Cl hydrogen bonds to generate [001] chains. To further investigate the inter­molecular inter­actions, a Hirshfeld surface analysis was performed, which showed that H⋯H, C⋯H/H⋯C and H⋯Cl/Cl⋯H contacts contribute 70.4, 20.0 and 8.3%, respectively.
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spelling pubmed-95358372022-10-13 Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride Schwab, Christoph Voss, Andreas Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Research Communications N-{[Diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary amino­methyl­silane that can be used, for example, to study carboli­thia­tion reactions of vinyl­silanes. Because the neutral compound did not crystallize well, the hydro­chloride salt, C(19)H(26)NSi(+)·Cl(−), was formed, in which the two chloride ions in the asymmetric unit have crystallographic [Image: see text] site symmetry. An unusually long Si—C bond of 1.9117 (10) Å is observed in the cation, which may be ascribed to electronic effects due to the β N(+) species. In the crystal, the cations and anions are linked by N—H⋯Cl hydrogen bonds to generate [001] chains. To further investigate the inter­molecular inter­actions, a Hirshfeld surface analysis was performed, which showed that H⋯H, C⋯H/H⋯C and H⋯Cl/Cl⋯H contacts contribute 70.4, 20.0 and 8.3%, respectively. International Union of Crystallography 2022-09-22 /pmc/articles/PMC9535837/ /pubmed/36250106 http://dx.doi.org/10.1107/S2056989022009112 Text en © Schwab et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Schwab, Christoph
Voss, Andreas
Strohmann, Carsten
Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
title Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
title_full Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
title_fullStr Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
title_short Crystal structure and Hirshfeld surface analysis of N-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
title_sort crystal structure and hirshfeld surface analysis of n-{[diphen­yl(vin­yl)sil­yl]meth­yl}-2-methyl­propan-2-ammonium chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535837/
https://www.ncbi.nlm.nih.gov/pubmed/36250106
http://dx.doi.org/10.1107/S2056989022009112
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