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Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride
N-{[Diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary aminomethylsilane that can be used, for example, to study carbolithiation reactions of vinylsilanes. Because the neutral compound did not crystallize well, the hydrochloride salt, C(19...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535837/ https://www.ncbi.nlm.nih.gov/pubmed/36250106 http://dx.doi.org/10.1107/S2056989022009112 |
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author | Schwab, Christoph Voss, Andreas Strohmann, Carsten |
author_facet | Schwab, Christoph Voss, Andreas Strohmann, Carsten |
author_sort | Schwab, Christoph |
collection | PubMed |
description | N-{[Diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary aminomethylsilane that can be used, for example, to study carbolithiation reactions of vinylsilanes. Because the neutral compound did not crystallize well, the hydrochloride salt, C(19)H(26)NSi(+)·Cl(−), was formed, in which the two chloride ions in the asymmetric unit have crystallographic [Image: see text] site symmetry. An unusually long Si—C bond of 1.9117 (10) Å is observed in the cation, which may be ascribed to electronic effects due to the β N(+) species. In the crystal, the cations and anions are linked by N—H⋯Cl hydrogen bonds to generate [001] chains. To further investigate the intermolecular interactions, a Hirshfeld surface analysis was performed, which showed that H⋯H, C⋯H/H⋯C and H⋯Cl/Cl⋯H contacts contribute 70.4, 20.0 and 8.3%, respectively. |
format | Online Article Text |
id | pubmed-9535837 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-95358372022-10-13 Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride Schwab, Christoph Voss, Andreas Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Research Communications N-{[Diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-amine, C(19)H(25)NSi, is a newly synthesized secondary aminomethylsilane that can be used, for example, to study carbolithiation reactions of vinylsilanes. Because the neutral compound did not crystallize well, the hydrochloride salt, C(19)H(26)NSi(+)·Cl(−), was formed, in which the two chloride ions in the asymmetric unit have crystallographic [Image: see text] site symmetry. An unusually long Si—C bond of 1.9117 (10) Å is observed in the cation, which may be ascribed to electronic effects due to the β N(+) species. In the crystal, the cations and anions are linked by N—H⋯Cl hydrogen bonds to generate [001] chains. To further investigate the intermolecular interactions, a Hirshfeld surface analysis was performed, which showed that H⋯H, C⋯H/H⋯C and H⋯Cl/Cl⋯H contacts contribute 70.4, 20.0 and 8.3%, respectively. International Union of Crystallography 2022-09-22 /pmc/articles/PMC9535837/ /pubmed/36250106 http://dx.doi.org/10.1107/S2056989022009112 Text en © Schwab et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Schwab, Christoph Voss, Andreas Strohmann, Carsten Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
title | Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
title_full | Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
title_fullStr | Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
title_short | Crystal structure and Hirshfeld surface analysis of N-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
title_sort | crystal structure and hirshfeld surface analysis of n-{[diphenyl(vinyl)silyl]methyl}-2-methylpropan-2-ammonium chloride |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535837/ https://www.ncbi.nlm.nih.gov/pubmed/36250106 http://dx.doi.org/10.1107/S2056989022009112 |
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