Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries

The cyclic stability of the MnO(x) cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn(3+) disproportionation produces Mn(2+) caused by Jahn Teller lattice distortion effect in the process of Zn(2+) inter/deintercalation. This mini review summarized bulk-phase and inter...

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Autores principales: Yang, Gaoqi, Wan, Houzhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9537755/
https://www.ncbi.nlm.nih.gov/pubmed/36212062
http://dx.doi.org/10.3389/fchem.2022.1000337
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author Yang, Gaoqi
Wan, Houzhao
author_facet Yang, Gaoqi
Wan, Houzhao
author_sort Yang, Gaoqi
collection PubMed
description The cyclic stability of the MnO(x) cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn(3+) disproportionation produces Mn(2+) caused by Jahn Teller lattice distortion effect in the process of Zn(2+) inter/deintercalation. This mini review summarized bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries from the regulation of bulk electronic state of manganese oxide improves its structural stability and the formation of beneficial SEI layer at the interface of electrolyte. It provides theoretical support for the design of manganese oxide cathode materials for aqueous zinc ion batteries with high stability.
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spelling pubmed-95377552022-10-08 Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries Yang, Gaoqi Wan, Houzhao Front Chem Chemistry The cyclic stability of the MnO(x) cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn(3+) disproportionation produces Mn(2+) caused by Jahn Teller lattice distortion effect in the process of Zn(2+) inter/deintercalation. This mini review summarized bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries from the regulation of bulk electronic state of manganese oxide improves its structural stability and the formation of beneficial SEI layer at the interface of electrolyte. It provides theoretical support for the design of manganese oxide cathode materials for aqueous zinc ion batteries with high stability. Frontiers Media S.A. 2022-09-23 /pmc/articles/PMC9537755/ /pubmed/36212062 http://dx.doi.org/10.3389/fchem.2022.1000337 Text en Copyright © 2022 Yang and Wan. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Yang, Gaoqi
Wan, Houzhao
Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries
title Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries
title_full Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries
title_fullStr Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries
title_full_unstemmed Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries
title_short Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnO(x) batteries
title_sort bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous zn-mno(x) batteries
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9537755/
https://www.ncbi.nlm.nih.gov/pubmed/36212062
http://dx.doi.org/10.3389/fchem.2022.1000337
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AT wanhouzhao bulkphaseandinterfacestabilitystrategiesofmanganeseoxidecathodesforaqueousznmnoxbatteries

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