Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers

The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric sy...

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Detalles Bibliográficos
Autores principales: Chao, Yang, Krishna, Akash, Subramaniam, Muthusamy, Liang, Dong‐Dong, Pujari, Sidharam P., Sue, Andrew C.‐H., Li, Guanna, Miloserdov, Fedor M., Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540147/
https://www.ncbi.nlm.nih.gov/pubmed/35819248
http://dx.doi.org/10.1002/anie.202207456
Descripción
Sumario:The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries.

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