Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers

The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric sy...

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Detalles Bibliográficos
Autores principales: Chao, Yang, Krishna, Akash, Subramaniam, Muthusamy, Liang, Dong‐Dong, Pujari, Sidharam P., Sue, Andrew C.‐H., Li, Guanna, Miloserdov, Fedor M., Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540147/
https://www.ncbi.nlm.nih.gov/pubmed/35819248
http://dx.doi.org/10.1002/anie.202207456
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author Chao, Yang
Krishna, Akash
Subramaniam, Muthusamy
Liang, Dong‐Dong
Pujari, Sidharam P.
Sue, Andrew C.‐H.
Li, Guanna
Miloserdov, Fedor M.
Zuilhof, Han
author_facet Chao, Yang
Krishna, Akash
Subramaniam, Muthusamy
Liang, Dong‐Dong
Pujari, Sidharam P.
Sue, Andrew C.‐H.
Li, Guanna
Miloserdov, Fedor M.
Zuilhof, Han
author_sort Chao, Yang
collection PubMed
description The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries.
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spelling pubmed-95401472022-10-14 Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers Chao, Yang Krishna, Akash Subramaniam, Muthusamy Liang, Dong‐Dong Pujari, Sidharam P. Sue, Andrew C.‐H. Li, Guanna Miloserdov, Fedor M. Zuilhof, Han Angew Chem Int Ed Engl Research Articles The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries. John Wiley and Sons Inc. 2022-07-29 2022-09-05 /pmc/articles/PMC9540147/ /pubmed/35819248 http://dx.doi.org/10.1002/anie.202207456 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Research Articles
Chao, Yang
Krishna, Akash
Subramaniam, Muthusamy
Liang, Dong‐Dong
Pujari, Sidharam P.
Sue, Andrew C.‐H.
Li, Guanna
Miloserdov, Fedor M.
Zuilhof, Han
Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
title Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
title_full Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
title_fullStr Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
title_full_unstemmed Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
title_short Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
title_sort sulfur–phenolate exchange: sufex‐derived dynamic covalent reactions and degradation of sufex polymers
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540147/
https://www.ncbi.nlm.nih.gov/pubmed/35819248
http://dx.doi.org/10.1002/anie.202207456
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