Synthesis of Hydrofluoroolefin‐Based Iodonium Reagent via Dyotropic Rearrangement and Its Utilization in Fluoroalkylation

[1,2]‐shift of atoms in alkyl fragments belongs to the class of dyotropic rearrangements. Various atoms, including halogens can be involved in the migration, however participation of iodine is unprecedented. Herein, we report our experimental and DFT studies on the oxidation triggered dyotropic rear...

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Detalles Bibliográficos
Autores principales: Csenki, János T., Tóth, Balázs L., Béke, Ferenc, Varga, Bálint, P. Fehér, Péter, Stirling, András, Czégény, Zsuzsanna, Bényei, Attila, Novák, Zoltán
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540448/
https://www.ncbi.nlm.nih.gov/pubmed/35876269
http://dx.doi.org/10.1002/anie.202208420

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540448/
https://www.ncbi.nlm.nih.gov/pubmed/35876269
http://dx.doi.org/10.1002/anie.202208420

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