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Recyclable Mn(I) Catalysts for Base‐Free Asymmetric Hydrogenation: Mechanistic, DFT and Catalytic Studies

We report here a mechanistic, DFT and catalytic study on a series of Mn(I) complexes 1, 2(a–d), 3, 4. The studies apprehended the requirements for Mn(I) complexes to be active in both asymmetric direct (AH) and transfer hydrogenations (ATH). The investigations disclosed 6 vital factors accelerating...

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Detalles Bibliográficos
Autores principales:	Jayaprakash, Harikrishnan, Coburger, Peter, Wörle, Michael, Togni, Antonio, Grützmacher, Hansjorg
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540457/ https://www.ncbi.nlm.nih.gov/pubmed/35652608 http://dx.doi.org/10.1002/chem.202201522

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