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Site‐Selective (Z)‐α‐Borylalkenyl Copper Systems for Nucleophilic Stereodefined Allylic Coupling

1,1‐Diborylalkenes can be transformed into (Z)‐skipped dienes through Cu(I)‐phosphine catalyzed allylic coupling reactions. The energetically preferred formation of (Z)‐α‐borylalkenyl copper (I) species and the subsequent nucleophilic attack, explains the stereoselective nucleophilic substitution wi...

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Detalles Bibliográficos
Autores principales:	Pujol, Mireia, Maza, Ricardo J., Salvado, Oriol, Carbó, Jorge J., Fernández, Elena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540588/ https://www.ncbi.nlm.nih.gov/pubmed/35857816 http://dx.doi.org/10.1002/anie.202208495

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