An Iron‐Catalyzed Route to Dewar 1,3,5‐Triphosphabenzene and Subsequent Reactivity

The application of an alkyne cyclotrimerization regime with an [Fe(salen)](2)‐μ‐oxo (1) catalyst to triphenylmethylphosphaalkyne (2) yields gram‐scale quantities of 2,4,6‐tris(triphenylmethyl)‐Dewar‐1,3,5‐triphosphabenzene (3). Bulky lithium salt LiHMDS facilitates a rearrangement of 3 to the 1,3,5‐...

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Detalles Bibliográficos
Autores principales: Barrett, Adam N., Diefenbach, Martin, Mahon, Mary F., Krewald, Vera, Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540597/
https://www.ncbi.nlm.nih.gov/pubmed/35851715
http://dx.doi.org/10.1002/anie.202208663

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540597/
https://www.ncbi.nlm.nih.gov/pubmed/35851715
http://dx.doi.org/10.1002/anie.202208663

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