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Carboxylate Catalyzed Isomerization of β,γ‐Unsaturated N‐Acetylcysteamine Thioesters

We demonstrate herein the capacity of simple carboxylate salts – tetrametylammonium and tetramethylguanidinium pivalate – to act as catalysts in the isomerization of β,γ‐unsaturated thioesters to α,β‐unsaturated thioesters. The carboxylate catalysts gave reaction rates comparable to those obtained w...

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Detalles Bibliográficos
Autores principales: Riuttamäki, Saara, Laczkó, Gergely, Madarász, Ádám, Földes, Tamás, Pápai, Imre, Bannykh, Anton, Pihko, Petri M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541288/
https://www.ncbi.nlm.nih.gov/pubmed/35604200
http://dx.doi.org/10.1002/chem.202201030

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