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On the Bonding Nature in the Crystalline Tri‐Thorium Cluster: Core‐Shell Syngenetic σ‐Aromaticity
A unique thorium‐thorium bond was observed in the crystalline tri‐thorium cluster [{Th(η(8)‐C(8)H(8))(μ(3)‐Cl)(2)}(3){K(THF)(2)}(2)](∞), though the claim of σ‐aromaticity for Th(3) bond has been questioned. Herein, a new type of core–shell syngenetic bonding model is proposed to describe the stabili...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541753/ https://www.ncbi.nlm.nih.gov/pubmed/35856937 http://dx.doi.org/10.1002/anie.202209658 |