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Molecular Ln(III)−H−E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb)

Following the alkane‐elimination route, the reaction between tetravalent aryl tintrihydride Ar*SnH(3) and trivalent rare‐earth‐metallocene alkyls [Cp*(2)Ln(CH{SiMe(3)}(2))] gave complexes [Cp*(2)Ln(μ‐H)(2)SnAr*] implementing a low‐valent tin hydride (Ln=Y, Lu; Ar*=2,6‐Trip(2)C(6)H(3), Trip=2,4,6‐tri...

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Detalles Bibliográficos
Autores principales: Widemann, Max, Aicher, Frederik S. W., Bonath, Martin, Eichele, Klaus, Maichle‐Mössmer, Cäcilia, Schubert, Hartmut, Sirsch, Peter, Anwander, Reiner, Wesemann, Lars
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541956/
https://www.ncbi.nlm.nih.gov/pubmed/35620817
http://dx.doi.org/10.1002/chem.202201032