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Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile‐ versus Proton‐Coupled Electron Transfer

Nitride complexes are key species in homogeneous nitrogen fixation to NH(3) via stepwise proton‐coupled electron transfer (PCET). In contrast, direct generation of nitrogenous organic products from N(2)‐derived nitrides requires new strategies to enable efficient reductive nitride transfer in the pr...

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Detalles Bibliográficos
Autores principales: Fritz, Maximilian, Rupp, Severine, Kiene, Ciara I., Kisan, Sesha, Telser, Joshua, Würtele, Christian, Krewald, Vera, Schneider, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542086/
https://www.ncbi.nlm.nih.gov/pubmed/35714100
http://dx.doi.org/10.1002/anie.202205922