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Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile‐ versus Proton‐Coupled Electron Transfer
Nitride complexes are key species in homogeneous nitrogen fixation to NH(3) via stepwise proton‐coupled electron transfer (PCET). In contrast, direct generation of nitrogenous organic products from N(2)‐derived nitrides requires new strategies to enable efficient reductive nitride transfer in the pr...
Autores principales: | Fritz, Maximilian, Rupp, Severine, Kiene, Ciara I., Kisan, Sesha, Telser, Joshua, Würtele, Christian, Krewald, Vera, Schneider, Sven |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542086/ https://www.ncbi.nlm.nih.gov/pubmed/35714100 http://dx.doi.org/10.1002/anie.202205922 |
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